Guowu Zhan, Yingling Hong, Fenfen Lu, Abdul-Rauf Ibrahim, Mingming Du, Daohua Sun, Jiale Huang, Qingbiao Li, Jun Li. Transition metal (Fe, Co) and organic silanol modified mesoporous titanium phosphates as catalysts for the oxidation of benzyl alcohol in water. Number of times cited according to CrossRef: Significant role of high-valent iron-oxo species in the degradation and detoxification of indomethacine. Effective dispersion of Au and Au–M (M=Co, Ni, Cu and Zn) bimetallic nanoparticles over TiO2 grafted SBA-15: Their catalytic activity on dehydroisomerization of α-pinene. Nikolaos Dimitratos, Jose A. Lopez-Sanchez, Graham J. Hutchings. Generation of [FeIIIOOH(L1)2](ClO4)2 (3) species, FIGURE S22 Ground state optimized geometry of complex 1 using B3LYP/LANL2DZ, TABLE S1 Cartesian coordinates for complex 1, TABLE S2 Percentage contribution of complex 1 in different orbitals, FIGURE S23 Experimental (red) and theoretical (black) absorption spectra of complex 1 (2x10−5 M) recorded in acetonitrile, TABLE S3 Major transition along with their orbital contribution in complex 1, FIGURE S24 Total electron density plot over the molecule calculated using B3LYP level, FIGURE S25 Ground state optimized geometry of complex 2 using B3LYP/LANL2DZ, TABLE S4 Cartesian coordinates for complex 2, TABLE S5 Percentage contribution of complex 2 in different orbitals, TABLE S6 Major transition along with their orbital contribution in complex 2, FIGURE S26 Complex 2 total electron density plot over the molecule calculated using B3, TABLE S7 Crystal data and data collection parameters for the complex 1 and complex 2, TABLE S8 Selected bond distances (Å) for complexes 2 and 3 with optimized DFT bond parameters in gas phase. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. Yan Zhang, Xinjiang Cui, Feng Shi, and Youquan Deng . Get article recommendations from ACS based on references in your Mendeley library. Polyaniline-Supported Zinc Oxide (ZnO) Nanoparticles: An Active and Stable Heterogeneous Catalyst for the Friedel–Crafts Acylation Reaction.,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Oxidation of Benzyl Alcohol over Nanoporous Au–CeO2 Catalysts Prepared from Amorphous Alloys and Effect of Alloying Au with Amorphous Alloys. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Supported Gold Nanoparticles as Catalysts for the Oxidation of Alcohols and Alkanes. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Water is used as a medium to replace toxic organic solvents. Active and Stable Platinum/Ionic Liquid/Carbon Nanotube Electrocatalysts for Oxidation of Methanol. Selective liquid phase benzyl alcohol oxidation over Cu-loaded LaFeO Saad Alabbad, S.F. 3 Lin Liu, Juanjuan Ma, Jiyin Xia, Luodan Li, Chunlong Li, Xiaobo Zhang, Junyan Gong, Zhiwei Tong. Enhanced selective oxidation of benzyl alcohol to benzaldehyde on mesopore created mordenite catalyst. Ashish Kumar, Vanama Pavan Kumar, Balla Putra Kumar, Venkataraman Vishwanathan, Komandur V. R. Chary. C-scorpionate Au(III) complexes as pre-catalysts for industrially significant toluene oxidation and benzaldehyde esterification reactions. 3 We use cookies to help provide and enhance our service and tailor content and ads. 64 publications. Lihua Jia, Sen Zhang, Fangna Gu, Yuan Ping, Xiangfeng Guo, Ziyi Zhong, Fabing Su. Yangming Lin, Kuang-Hsu Tim Wu, Linhui Yu, Saskia Heumann, Dang Sheng Su. Concerning the benzyl alcohol oxidation to benzaldehyde in the absence of alkali, early reports deal principally with liquid phase reactions which rarely reach the total conversion and show a selectivity in the range of 90–100% in spite of a quite low TOF , , , , . Ashish Kumar, Vanama Pavan Kumar, Amirineni Srikanth, Venkataraman Vishwanathan, Komandur V. R. Chary. Selective Oxidation of Benzyl Alcohol to Benzaldehyde Adapted from literature by Keti Assor, Irvin Levy, Erin Thames and Rowan Walker Background Traditionally oxidation of alcohols to aldehydes requires the use of hazardous, heavy-metal reagents, such as pyridinium chlorochromate (PCC). N Oxidation of Benzyl Alcohol to Benzaldehyde by, Chemical Engineering and Process Development Division, National Chemical Laboratory, Pune 411008, India, Department of Applied Chemistry, RMIT University, Melbourne 3000, Australia. 3 ESI − MS analysis also helped to understand the generation of intermediate species like FeIII−OOH and FeIV=O. Journal of Polymer Science Part A: Polymer Chemistry. Assal, Mujeeb Khan, Abdulrahman Alwarthan, M. Rafiq H. Siddiqui. Journal of Industrial and Engineering Chemistry. and you may need to create a new Wiley Online Library account. However, the Au3+ species are mostly responsible for the high catalytic activity in the oxidation process. Catalytic oxidation of benzyl alcohol over manganese oxide supported on MCM-41 zeolite. Nikolaos Dimitratos, Ceri Hammond, Peter Wells. Dealloyed forces: Nanoporous gold, made by selective etching of Ag–Au alloys, exhibits extraordinary catalytic activity towards the gas‐phase oxidation of benzyl alcohol to form benzaldehyde with selectivities up to 98.2 %, using molecular oxygen as an oxidant … Vapor Phase Oxidation of Benzyl Alcohol over Nano Au/SBA-15 Catalysts: Effect of Preparation Methods. An efficient and reusable vanadium based catalytic system for room temperature oxidation of alcohols to aldehydes and ketones. supported gold-based bimetallic nanoparticles. Free solvent oxidation of molecular benzyl alcohol by newly synthesized AuPd/titania catalysts. Learn about our remote access options, Department of Chemistry, IIT Roorkee, Roorkee, 247667 Uttarakhand, India. Adil, M.E. Volkan Çakır, Ece Tuğba Saka, Zekeriya Bıyıklıoğlu, Halit Kantekin. Girdhar Joshi, Sukalyan Bhadra, Sudip Ghosh, Manoj K. Agrawal, Bishwajit Ganguly, Subbarayappa Adimurthy, Pushpito K. Ghosh and Brindaban C. Ranu . Mohd Izham bin Saiman, Gemma L. Brett, Ramchandra Tiruvalam, Michael M. Forde, Kate Sharples, Adam Thetford, Robert L. Jenkins, Nikolaos Dimitratos, Jose A. Lopez-Sanchez, Damien M. Murphy, Donald Bethell, David J. Willock, Stuart H. Taylor, David W. Knight, Christopher J. Kiely, Graham J. Hutchings.